Erratum: Ultra stable self-assembled monolayers of N-heterocyclic carbenes on gold

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N‐Heterocyclic Carbene Self‐assembled Monolayers on Copper and Gold: Dramatic Effect of Wingtip Groups on Binding, Orientation and Assembly

Self-assembled monolayers of N-heterocyclic carbenes (NHCs) on copper are reported. The monolayer structure is highly dependent on the N,N-substituents on the NHC. On both Cu(111) and Au(111), bulky isopropyl substituents force the NHC to bind perpendicular to the metal surface while methyl- or ethyl-substituted NHCs lie flat. Temperature-programmed desorption studies show that the NHC binds to...

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N-Heterocyclic carbenes

The N-heterocyclic carbenes (NHC) now hold a preferredligand status in organic and organometallic chemistry. Their role in catalysis continues to grow. When the editorial staff at the Beilstein Journal of Organic Chemistry contacted me to act as a guest editor for the thematic series “N-Heterocyclic carbenes”, I was more than happy to accept what appeared to me to be a simple and exciting endea...

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ژورنال

عنوان ژورنال: Nature Chemistry

سال: 2014

ISSN: 1755-4330,1755-4349

DOI: 10.1038/nchem.1950